河南农业科学 ›› 2022, Vol. 51 ›› Issue (1): 1-10.DOI: 10.15933/j.cnki.1004-3268.2022.01.001
赵淑蘅1,2,李卓洁1,刘晓锋1,胡建军1,2,丁严博1
收稿日期:
2021-09-12
出版日期:
2022-01-15
发布日期:
2022-03-17
通讯作者:
胡建军(1977-),男,河南信阳人,教授,博士,主要从事生物质资源化利用方面研究。E-mail:hu.jianjun@163.com
作者简介:
赵淑蘅(1987-),女,河南辉县人,讲师,博士,主要从事生物质热化学转化研究工作。E-mail:zhaosh09@163.com
基金资助:
ZHAO Shuheng1,2,LI Zhuojie1,LIU Xiaofeng1,HU Jianjun1,2,DING Yanbo1
Received:
2021-09-12
Published:
2022-01-15
Online:
2022-03-17
摘要: 木醋液作为生物质热解制炭过程中的高价值酸性副产物,富含酸、醇、酚、醛、酯、醚等多种有机化合物以及少量金属元素,具有极高的应用价值。在木醋液的原料中,秸秆木质素含量较低、品质略差,因而秸秆木醋液的发展与应用较为缓慢。但秸秆木醋液的研究对农业废弃物的利用具有重要意义,有广阔的发展前景。主要介绍了秸秆木醋液的粗制及精制工艺,概述了其组成及理化性质,并综述其在农业、医药卫生及其他领域的研究及应用进展,为秸秆木醋液的进一步发展及高效利用提供参考。
中图分类号:
赵淑蘅, 李卓洁, 刘晓锋, 胡建军, 丁严博. 秸秆木醋液的制备及应用研究进展[J]. 河南农业科学, 2022, 51(1): 1-10.
ZHAO Shuheng, LI Zhuojie, LIU Xiaofeng, HU Jianjun, DING Yanbo. Research Progress on Preparation and Application of Straw Wood Vinegar[J]. Journal of Henan Agricultural Sciences, 2022, 51(1): 1-10.
[1]MATHEW S,ZAKARIA Z A.Pyroligneous acid:The smoky acidic liquid from plant biomass[J].Applied Microbiology & Biotechnology,2015,99(2):611‐622. [2]MARUMOTO S,YAMAMOTO S P,NISHIMURUA H,et al.Identification of a germicidal compound against picornavirus in bamboo pyroligneous acid[J].Journal of Agricultural & Food Chemistry,2012,60(36) :9106‐9111. [3]YATAGAI M,NISHIMOTO M,HORI K,et al.Termiticidal activity of wood vinegar,its componentsand their homologues[J].Journal of Wood Science,2002,48(4):338‐342. [4]MATHEW S,ZAKARIA Z A,MUSA N F.Antioxidant property and chemical profile of pyroligneous acid from pineapple plant waste biomass[J].Process Biochemistry,2015,50(11):1985‐1992. [5]WU Q M,ZHANG S Y,HOU B X,et al.Study on the preparation of wood vinegar from biomass residues by carbonization process[J].Bioresource Technology,2015,179(3):98‐103. [6]胡小凤,李卓,梁春莉.木醋液应用研究进展[J].辽宁农业职业技术学院学报,2019,21(5):1‐3. HU X F,LI Z,LIANG C L.Research progress of the application of wood vinegar[J].Journal of Liaoning Agricultural Technical College,2019,21(5):1‐3. [7]潘琴,冮洁,许英梅,等.木醋液的制备及其应用研究进展[J].大连民族大学学报,2020,37(3):9‐15. PAN Q,GANG J,XU Y M,et al.Research progress on preparation and application of wood vinegar liquor[J].Journal of Dalian Minzu University,2020,37(3):9‐15. [8]钱慧娟. 木醋液的制造及其应用[J].世界林业研究,1994(2):59‐63. QIAN H J.A preliminary discussion on the lignoacetic liquid:Its development and utilization[J].World Forestry Research,1994(2):59‐63. [9]刘长风,李敏,高品一,等.木醋液的来源、成分及其应用研究进展[J].中国农学通报,2016,32(1):28‐32. LIU C F,LI M,GAO P Y,et al.Research progress of source,chemical compositions and application of wood vinegar[J].Chinese Agricultural Science Bulletin,2016,32(1):28‐32. [10]刘哲,田文善,杨朝辉,等.喷施木醋酸对苹果树叶片和果实品质的影响[J].西北农业学报,2018,27(2):213‐219. LIU Z,TIAN W S,YANG Z H,et al.Effect of wood vinegar on leaf growth and fruit quality of apple trees[J].Acta Agriculturae Boreali‐Occidentalis Sinica,2018,27(2):213‐219. [11]梁凤臣,张丽丽,李艳,等.木醋液浸种对西葫芦种子萌发和幼苗生长的影响[J].中国农学通报,2016,32(16):51‐55. LIANG F C,ZHANG L L,LI Y,et al.Effect of wood vinegar on seed viability and seedling growth of summer squash[J].Chinese Agricultural Science Bulletin,2016,32(16):51‐55. [12]冯馨慧,王海英,刘志明.木醋液对长白落叶松种子萌发的影响[J].广东化工,2018,45(3):23‐24. FENG X H,WANG H Y,LIU Z M.Effect of wood vinegar on seed germination of Larix olgensis[J].Guangdong Chemical Industry,2018,45(3):23‐24. [13]孙付超,袁静,刘洪波,等.3种生物质醋液的除草效果研究[J].农药,2018,57(12):928‐931. SUN F C,YUAN J,LIU H B,et al.Weed control effect of three biomass gasification liquids[J].Agrochemicals,2018,57(12):928‐931. [14]AGUIRRE J L,BAENA J,MARTIN M T,et al.Composition,ageing and herbicidal properties of wood vinegar obtained through fast biomass pyrolysis[J].Energies,2020,13(10):1‐17. [15]安鑫南. 林产化学工艺学[M].北京:中国林业出版社,2002:55‐57. AN X N.Chemical technology of forest products[M].Beijing:China Forestry Publishing Press,2002:55‐57. [16]周建斌. 木材热解与活性炭生产[M].北京:中国物资出版社,2003. ZHOU J B.Wood pyrolysis and activated carbon production[M].Beijing:China Materials Publishing Press,2003. [17]王才威,张守玉,杨东杰,等.木醋液制备及形成机理研究进展[J].化工进展,2020,39(9):3723‐3738. WANG C W,ZHANG S Y,YANG D J,et al.Research advance in preparation and formation mechanism of wood vinegar[J].Chemical Industry and Engineering Progress,2020,39(9):3723‐3738. [18]张利亚,刘霞,张佩.小麦秸秆木醋液成分及抑菌效果研究[J].江苏农业科学,2020,48(18):219‐222. ZHANG L Y,LIU X,ZHANG P. Study on composition and antibacterial effect of wheat straw wood vinegar[J].Jiangsu Agricultural Sciences,2020,48(18):219‐222. [19]杨頔,刘学贵,年中峰,等.木醋液中酚类物质的富集及其提取工艺的研究[J].宁夏农林科技,2015,56(4):55‐58. YANG D,LIU X G,NIAN Z F,et al.A study of extraction process of enriched phenols from wood vinegar[J].Ningxia Journal of Agriculture and Forestry Science and Technology,2015,56(4):55‐58. [20]WANG Z,LIN W G,SONG W L,et al.Preliminary investigation on concentrating of acetol from wood vinegar [J].Energy Conversion and Management,2010,51(2):346‐349. [21]常青,王永亮,张强,等.木醋液对茄子种子发芽的促进作用[J].山西农业科学,2018,46(8):1269‐1273. CHANG Q,WANG Y L,ZHANG Q,et al.Promoting effect of wood vinegar on germination of eggplant seed[J].Journal of Shanxi Agricultural Sciences,2018,46(8):1269‐1273. [22]翟梅枝,何文君,王磊,等.3种木醋液化学成分与抑菌活性研究[J].西北植物学报,2010,30(6):1247‐1252. ZHAI M Z,HE W J,WANG L,et al.Chemical compositions and antimicrobial activities of three wood vinegars[J].Acta Botanica Boreali‐Occidentalia Sinica,2010,30(6):1247‐1252. [23]常青,王永亮,杨治平,等.木醋液对土壤pH、EC与茄子叶片光合特性及根系发育的影响[J].农业资源与环境学报,2019,36(3):322‐328. CHANG Q,WANG Y L,YANG Z P,et al.Effects of wood vinegar on soil pH,EC,and the photosynthetic characteristics of eggplant leaves and root development[J].Journal of Agricultural Resources and Environment,2019,36(3):322‐328. [24]GUILLEN M D,MANZANOS M J,IBARGOITIA M L.Carbohydrate and nitrogenated compounds in liquid smoke flavorings[J].Journal of Agricultural and Food Chemistry,2001,49(5):2395‐2403. [25]周建斌,邓丛静,陈金林,等.玉米秸秆炭化产物的性能及应用[J].东北林业大学学报,2008,36(12):59‐61. ZHOU J B,DENG C J,CHEN J L,et al.Property and application of corn straw carbonized products[J].Journal of Northeast Forestry University,2008,36(12):59‐61. [26]周岭,万传星,蒋恩臣.棉秆与杂木木醋液成分比较分析[J].华南农业大学学报,2009,30(2):22‐25. ZHOU L,WAN C X,JIANG E C.Comparative analysis of the cotton stalk vinegar and miscellaneous wood vinegar[J].Journal of South China Agricultural University,2009,30(2):22‐25. [27]王建刚. 稻壳木醋液化学成分气相色谱质谱分析[J].安徽农业科学,2017,45(31):15‐17. WANG J G.Chemical constitution analysis of wood vinegar from rice husk by gas chromatography‐mass spectrometry [J].Journal of Anhui Agricultural Sciences,2017,45(31):15‐17. [28]周建斌,张合玲,叶汉玲,等.几种秸秆醋液组分中活性物质的分析[J].生物质化学工程,2009,43(2):34‐36. ZHOU J B,ZHANG H L,YE H L,et al.Analysis of active substances of several kinds of straw vinegar[J].Biomass Chemical Engineering,2009,43(2):34‐36. [29]陈萍,邵立兴,王建刚.花生壳木醋液有机成分分析[J].山东化工,2017,46(24):86‐88. CHEN P,SHAO L X,WANG J G.Analysis on the organic components of wood vinegar from peanut shell[J].Shandong Chemical Industry,2017,46(24):86‐88. [30]郭根茂,黄青,王青青,等.基于实验与文献研究热解温度和原料对木醋液组分的影响[J].天然产物研究与开发,2021,33(8):1371‐1381. GUO G M,HUANG Q,WANG Q Q,et al.Effects of pyrolysis temperature and raw materials on composition of wood vinegar based on experiments and literature[J].Natural Products Research and Development,2021,33(8):1371‐1381. [31]ZHANG Z Z,NING S R,LI Q B,et al.Levels and risk assessment of polycyclic aromatic hydrocarbons in wood vinegars from pyrolysis of biomass [J].Chemosphere,2021,278:130453. [32]刘标,陈应泉,何涛,等.农作物秸秆热解多联产技术的应用[J].农业工程学报,2013,29(16):213‐219. LIU B,CHEN Y Q,HE T,et al.Application of cogeneration technology of gas‐liquid‐solid products pyrolyzed from crop straw[J].Transactions of the Chinese Society of Agricultural Engineering,2013,29(16):213‐219. [33]解秋,王敏,张旭辉,等.木醋液:生物质炭基肥对玉米苗期生长及氮素利用率的影响[J].土壤通报,2018,49(5):1165‐1169. XIE Q,WANG M,ZHANG X H,et al.Effect of wood vinegar‐biochar as base fertilizers on the growth and nitrogen utilization of maize at seeding stage[J].Chinese Journal of Soil Science,2018,49(5) :1165‐1169. [34]LASHARI M S,YE Y X,JI H S,et al.Biochar‐manure compost in conjunction with pyroligneous solution alleviated salt stress and improved leaf bioactivity of maize in a saline soil from central China:A 2‐year field experiment[J].Journal of the Science of Food and Agriculture,2015,95(6):1321‐1327. [35]孙显旻,国艳春,曾路生,等.叶面喷施不同浓度木醋液对棉花产量和光合利用效率的影响[J].中国棉花,2020,47(12):7‐12,26. SUN X M,GUO Y C,ZENG L S,et al.Effect of foliar applications of different concentrations of wood vinegar on cotton yield and photosynthetic utilization efficiency[J].China Cotton,2020,47(12):7‐12,26. [36]董娟,付潘潘,刘晓雨,等.生物质炭:木醋液包衣剂对玉米幼苗生长及抗氧化酶活性的影响[J].土壤通报,2014,45(5):1207‐1212. DONG J,FU P P,LIU X Y,et al.Effects of biochar and wood vinegar coating agent on maize seedling growth and the antioxidant enzyme activities[J].Chinese Journal of Soil Science,2014,45(5):1207‐1212. [37]于志民,孙磊.喷施木醋液对孔雀草影响的研究[J].国土与自然资源研究,2013,142(1):84‐85. YU Z M,SUN L.Study on the effects of spraying wood vinegar on maidenhair[J].Territory & Natural Resources Study,2013,142(1):84‐85. [38]张利亚,王留成,刘霞,等.木醋液作为叶面肥对番茄生长的调节效果[J].浙江农业科学,2019,60(2):231‐233. ZHANG L Y,WANG L C,LIU X,et al.Regulation effect of wood vinegar as foliar fertilizer on tomato growth[J].Journal of Zhejiang Agricultural Sciences,2019,60(2):231‐233. [39]周建云,覃青青,刁朝强,等.不同木醋液对干旱胁迫烤烟生长及生理的影响[J].西南农业学报,2020,33(10):2232‐2236. ZHOU J Y,QIN Q Q,DIAO C Q,et al.Effects of different wood vinegar on growth and physiology of flue‐cured tobacco under drought stress[J].Southwest China Journal of Agricultural Sciences,2020,33(10):2232‐2236. [40]闫钰,陆鑫达,李恋卿,等.秸秆热裂解木醋液成分及其对辣椒生长及品质的影响[J].南京农业大学学报,2011,34(5):58‐62. YAN Y,LU X D,LI L Q,et al.Components of pyroligneous solution from straw pyrolysis and its effect on growth and quality of pepper spice[J].Journal of Nanjing Agricultural University,2011,34(5):58‐62. [41]SUN X M,GUO Y C,ZENG L S,et al.Combined urea humate and wood vinegar treatment enhances wheat‐maize rotation system yields and nitrogen utilization efficiency through improving the quality of saline‐alkali soils[J].Journal of Soil Science and Plant Nutrition,2021,21(2):1759‐1770. [42]陈秀玲,赵红晓,李东玉,等.两种秸秆醋液对尖孢镰刀菌和立枯丝核菌的抑菌作用[J].基因组学与应用生物学,2020,39(2):621‐628. CHEN X L,ZHAO H X,LI D Y,et al.Inhibition effects of two kinds of straw vinegar on Fusarium oxysporum and Rhizoctonia solani[J].Genomics and Applied Biology,2020,39(2):621‐628. [43]李维蛟,李强,胡先奇.木醋液的杀线活性及对根结线虫病的防治效果研究[J].中国农业科学,2009,42(11):4120‐4126. LI W J,LI Q,HU X Q.Nematicidal activity and control efficiency of pyroligneous liquor on Meloidogyne spp.[J]. Scientia Agricultura Sinica,2009,42(11):4120‐4126. [44]GAO T,BIAN R J,JOSEPH S D,et al.Wheat straw vinegar:A more cost‐effective solution than chemical fungicides for sustainable wheat plant protection[J].Science of the Total Environment,2020,725(7):138359. [45]康晓宇,韩篷慧,张先,等.不同作物秸秆热解液对辣椒炭疽菌的抑制及其生理指标的影响[J].延边大学农学学报,2019,41(3):29‐35. KANG X Y,HAN P H,ZHANG X,et al.Effects of different crop straw pyrolysis liquid on inhibition of Colletotrichum capsici and its physiological indexes[J].Agricultural Science Journal of Yanbian University,2019,41(3):29‐35. [46]WEI Q,MA X H,DONG J E.Preparation,chemical constituents and antimicrobial activity of pyroligneous acids from walnut tree branches[J].Journal of Analytical and Applied Pyrolysis,2010,87(1):24‐28. [47]彭美芳,陈文学,李宇真,等.草果提取物对金黄色葡萄球菌抑菌机制的初探[J].食品工业科技,2013,34(24):79‐82. PENG M F,CHEN W X,LI Y Z,et al.Antibacterial mechanism of extract from Amomum tsao-ko on Staphylococcus aureus[J].Science and Technology of Food Industry,2013,34(24):79‐82. [48]TIILIKKALA K,FAGERNAS L,TIILIKKALA J.History and use of wood pyrolysis liquids as biocide and plant protection produc[t J].Open Agriculture Journal,2010,4(12):111‐118. [49]李文哲,朱巧银,范金霞,等.不同氮源及木醋液对沼渣堆肥的影响[J].环境工程学报,2016,10(10):5861‐5866. LI W Z,ZHU Q Y,FAN J X,et al.Effects of addition different nitrogen and wood vinegar on biogas residue composting[J].Chinese Journal of Environmental Engineering,2016,10(10):5861‐5866. [50]刘霞,张利亚.两种木醋液对鸡粪及污泥的臭气降解试验报告[J].当代畜牧,2019,452(12):18‐21. LIU X,ZHANG L Y.Odor degradation test of chicken manure and sludge by two kinds of wood vinegar[J].Contemporary Animal Husbandry,2019,452(12):18‐21. [51]秦翠兰,王磊元,刘飞,等.木醋液添加牛粪堆肥过程容重时空层次变化及水分时空变化的灰色关联分析[J].江苏农业科学,2016,44(4):482‐485. QIN C L,WANG L Y,LIU F,et al.Grey correlation analysis of spatiotemporal variation of bulk density and water content in the composting process of adding cow dung to wood vinegar[J].Jiangsu Agricultural Sciences,2016,44(4):482‐485. [52]刘飞,周岭.棉秆木醋液对牛粪堆肥过程中CH4和CO2排放的影响[J].江苏农业科学,2015,43(9):364‐369. LIU F,ZHOU L. Effects of wood vinegar from cotton stalk on CH4 and CO2 emissions during composting ofcow manure[J].Jiangsu Agricultural Sciences,2015,43(9):364‐369. [53]王磊元,刘飞,秦翠兰,等.木醋液对牛粪堆肥理化性质的影响[J].中国农机化学报,2015,36(3):296‐300. WANG L Y,LIU F,QIN C L,et al.Influence of wood vinegar on the physicochemical properties of cow manure composting[J].Journal of Chinese Agricultural Mechanization,2015,36(3):296‐300. [54]MATHEW S,ZAKARIA Z A,MUSA N F.Antioxidant property and chemical profile of pyroligneous acid from pineapple plant waste biomass[J].Process Biochemistry,2015,50(11):1985‐1992. [55]LOO A Y,KASSIM J N,IBRAHIM D.Antioxidant and radical scavenging activities of the pyroligneous acid from a mangrove plant,Rhizophora apiculata[J].Food Chemistry,2007,104(1):300‐307. [56]VITT S M,HIMELBLOOM B H,CRAPO C A.Inhibition of Listeria innocua and L.monocytogenes in a laboratory medium and cold‐smoked salmon containing liquid smoke[J].Journal of Food Safety,2010,21(2):111‐125. [57]LI Z C,ZHANGZ Q,WU L J,et al.Characterization of five kinds of wood vinegar obtained from agricultural and forestry wastes and identification of major antioxidants in wood vinegar[J].Chemical Research in Chinese Universities,2019,35(1):12‐20. [58]刘梦帆,郝润琴,郑晓伟,等.木醋液的抗氧化性和抑菌活性研究进展[J].安徽农业科学,2021,49(9):15‐21,31. LIU M F,HAO R Q,ZHENG X W,et al.Research progress on antioxidant and antibacterial activities of wood vinegar [J].Journal of Anhui Agricultural Sciences,2021,49(9):15‐21,31. [59]蒋宏伟,时国峰,赵拓,等.木醋液处理玉米秸秆及其饲喂肉牛效果[J].中国牛业科学,2017,43(4):34‐36. JIANG H W,SHI G F,ZHAO T,et al.Effect of corn stalks treated by wood vinegar on feeding in beef cattle [J].China Cattle Science,2017,43(4):34‐36. [60]张君正,王巍,张敏.木醋液对育肥猪肉质性状的影响[J].黑龙江畜牧兽医,2010,354(7):95‐97. ZHANG J Z,WANG W,ZHANG M.Effect of wood vinegar on meat quality characters of finishing pigs[J].Heilongjiang Animal Science and Veterinary Medicine,2010,354(7):95‐97. [61]李占超.木醋液的分离纯化及在食品和环境领域中的应用研究[D].吉林:吉林大学,2019. LI Z C. Study on separation and purification of wood vinegar and its application in food and environment[D].Jilin:Jilin University,2019. [62]FENG Y F,LI D T,SUN H J,et al.Wood vinegar and biochar co‐application mitigates nitrous oxide and methane emissions from rice paddy soil:A two‐year experiment[J].Environmental Pollution,2020,267:115403. [63]SUN S,GAO Z T,LI Z C,et al.Effect of wood vinegar on adsorption and desorption of four kinds of heavy(loid) metals adsorbents[J].Chinese Journal of Analytical Chemistry,2020,48(2):e20013‐e20020. [64]郭雅妮,丁玮,薛中福,等.木醋液制环保型融雪剂技术与应用研究[J].辽宁化工,2014,43(8):1019‐1020,1023. GUO Y N,DING W,XUE Z F,et al.Preparation of environmental friendly snow‐melting agent from wood vinegar and its application[J].Liaoning Chemical Industry,2014,43(8):1019‐1020,1023. [65]梁筱曼,高建民,陈瑶.万寿菊秸秆醋液的制备及对月季切花的保鲜作用[J].东北林业大学学报,2017,45(1):41‐46. LIANG X M,GAO J M,CHEN Y.Chemical compositions of vinegar from abandoned marigold straw and its effect on preservation of cut roses[J].Journal of Northeast Forestry University,2017,45(1):41‐46. [66]WANG J Q,POTOROKO I,TSIRULNICHENKO L.Wood vinegar and chitosan compound preservative affects on fish balls stability[J].Food Bioscience,2021,42:101102. [67]薛桂新,黄世臣,宋益冬.木醋液对桃黑根霉抑菌作用和对久保桃保鲜效果的研究[J].延边大学农学学报,2013,35(2):123‐130. XUE G X,HUANG S C,SONG Y D.Study of wood vinegar on inhibition and keeping‐fresh effect of R.nigrican Ehrenb of peach and Prurms persica[J].Agricultural Science Journal of Yanbian University,2013,35(2):123‐130. |
[1] | 马宇, 王硕立, 赵曦, 侯冰清, 薛子钟, 张扬, 习红昂, 程玉渊, 时向东, 邢雪霞. 保水剂对豫西南半湿润区雪茄烟田耕层土壤理化性质及烟株生长发育的影响[J]. 河南农业科学, 2024, 53(2): 46-55. |
[2] | 贾云超, 黄达, 王喜枝, 闫军营, 王立河. 长期定位施氯对3 种质地土壤理化性质及作物产量的影响[J]. 河南农业科学, 2023, 52(7): 81-89. |
[3] | 许豆豆, 贺云新, 李飞, 刘爱玉, 周仲华. 间套作模式在棉田上的研究进展[J]. 河南农业科学, 2023, 52(6): 1-11. |
[4] | 李勇辉, 张其钢, 雷婷, 严乃胜, 柳青, 唐国文. 云南桑园昆虫群落组成及时间生态位分析[J]. 河南农业科学, 2023, 52(4): 90-98. |
[5] | 黎日辉, 钟晓敏, 段鑫垚, 颜亚赛, 王琳, 王华, 李华. 极简化生态栽培模式对贵人香葡萄园土壤质量的影响[J]. 河南农业科学, 2023, 52(12): 127-135. |
[6] | 阮文晓, 傅敏杰, 朱月清, 王云霞, 庄道山, 郑文, 张萼, 朱志玉, 朱祝军, 吴建国. UV-B 多光谱补光对多肉植物观赏特性与理化性质的影响[J]. 河南农业科学, 2022, 51(6): 126-133. |
[7] | 代玉荣, 李云红, 穆立蔷, 吴进. 根围促生细菌配施生物质炭对辣椒生长和土壤理化性质的影响[J]. 河南农业科学, 2022, 51(5): 62-70. |
[8] | 李天才, 余米, 江瑞, 赵晴云, 付梅, 苏胜齐. 紫色土池塘养殖底泥理化性质变化及营养沉积过程[J]. 河南农业科学, 2022, 51(4): 151-159. |
[9] | 梁路, 张卫杰, 徐博涵, 庄秋丽, 姜秀芳, 黄玉波. 有机无机肥配施影响土壤肥力与土壤环境的研究进展[J]. 河南农业科学, 2022, 51(3): 1-11. |
[10] | 宋宇. 稻蟹共生系统根际土壤菌群组成及主要代谢通路分析[J]. 河南农业科学, 2022, 51(3): 73-83. |
[11] | 周颖, 周鑫伟, 郑听, 熊鹏飞, 张家春. 生物炭对药用植物生长影响的研究进展[J]. 河南农业科学, 2022, 51(1): 11-20. |
[12] | 张怡辉, 赵鑫龙, 付亚伟, 康相涛, 李孝法, 李东华, 蒋瑞瑞. 日粮添加草本生物调理剂对产蛋后期固始鸡肉品质和营养价值的影响[J]. 河南农业科学, 2022, 51(1): 125-133. |
[13] | 马嘉俊, 吴英华, 李璿, 李梅兰, 侯雷平. 白菜NPF 基因家族成员的鉴定及其生物信息学分析[J]. 河南农业科学, 2021, 50(9): 117-127. |
[14] | 高强, 宓文海, 夏斯琦, 刘明月, 毛伟, 居静, 赵海涛. 长期不同施肥措施下黄泥田水稻土团聚体组成、稳定性及养分分布特征[J]. 河南农业科学, 2021, 50(6): 70-81. |
[15] | 刘汉成, 孔照霞, 隆雪萍, 李保成, 马小梅, 扎西宗吉, 刘晶. 唐古特大黄根部土壤理化性质和微生物群落组成研究[J]. 河南农业科学, 2021, 50(4): 56-65. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||