贵州典型黄壤土中有机质和碳酸钙对Cd2+吸附解吸特征的影响

doi:10.15933/j.cnki.1004-3268.2021.05.008

河南农业科学 ›› 2021, Vol. 50 ›› Issue (5): 57-63.DOI: 10.15933/j.cnki.1004-3268.2021.05.008

贵州典型黄壤土中有机质和碳酸钙对Cd²⁺吸附解吸特征的影响

陈芬^1,2，余高^1,2，张红丽³，侯建伟²

（1.农业农村部产地环境污染防控重点实验室/天津市农业环境与农产品安全重点实验室，天津 300191；2.铜仁学院农林工程与规划学院，贵州铜仁 554300；3.国信司南(北京)地理信息技术有限公司，北京 100048）

收稿日期:2020-11-24 出版日期:2021-05-15 发布日期:2021-05-15
通讯作者: 余高 (1988-)，男，湖南益阳人，讲师，硕士，主要从事土壤重金属污染修复研究。E-mail:httywwwyu1014@sina.com
作者简介:陈芬(1987-)，女，山西平陆人，副教授，博士，主要从事土壤重金属污染修复研究。E-mail:chenfen2018@126.com
基金资助:
农业农村部产地环境污染防控重点实验室开放基金项目（19cdhj-5) ；贵州省大学生创新创业训练计划项目（S202010665023）；贵州省教育厅自然科学基金资助项目（黔教合 KY字［2018］349）

Effect of Organic Matter and Calcium Carbonate on Absorption-Desorption Characteristics of Cd²⁺ in Guizhou Yellow Loam Soil

CHEN Fen^1,2, YU Gao^1,2, ZHANG Hongli³, HOU Jianwei²

(1.Key Laboratory of Original Agro-environmental Pollution Prevention and Control,Ministry of Agriculture and Rural Affairs/Tianjin Key Laboratory of Agro-environment and Product-Safe,Tianjin 300191,China; 2.College of Agroforestry Engineering and Planning,Tongren University,Tongren 554300,China; 3.Geo-Compass Information Technology Co.,Ltd.,Beijing 100048,China)

Received:2020-11-24 Published:2021-05-15 Online:2021-05-15

摘要/Abstract

摘要： 为了研究去除有机质及碳酸钙前后黄壤土对Cd²⁺的吸附解吸特性，采用序批平衡法进行原土、去有机质土及去碳酸钙土对Cd²⁺的吸附解吸试验，用Langmuir和 Freundlich型吸附等温方程对试验吸附数据进行拟合，研究有机质和碳酸钙对Cd²⁺吸附解吸的影响。结果表明，3种土壤对Cd²⁺吸附量均随平衡溶液中Cd²⁺质量浓度的增加而增加，Cd²⁺吸附率随Cd²⁺初始质量浓度的增加呈先升高后降低的趋势，且Cd²⁺吸附量和吸附率均呈现出原土＞去碳酸钙土＞去有机质土的趋势。去有机质土和去碳酸钙土中Cd²⁺吸附等温线不适合用Langmuir方程描述，而Freundlich方程可较好地描述3种土壤对Cd²⁺的等温吸附过程。黄壤中Cd²⁺解吸量和解吸率均随Cd²⁺初始质量浓度的升高而增大，且Cd²⁺解吸量和解吸率均呈现出去有机质土＞去碳酸钙土＞原土的趋势。黄壤中Cd²⁺解吸量与吸附量均呈极显著正相关（P＜0.01）。当Cd²⁺吸附量一定时，3种土壤中Cd²⁺解吸量表现为去有机质土＞去碳酸钙土＞原土。由此可见，在贵州偏酸性典型黄壤中，有机质对Cd²⁺吸附解吸行为的影响明显大于碳酸钙。

关键词: 贵州黄壤土, Cd²⁺, 有机质, 碳酸钙, 吸附, 解吸

Abstract: In order to understand absorption-desorption characteristics of Cd²⁺ before and after removal of organic matter and calcium carbonate, the laboratory batch experiments were conducted to study the absorption-desorption characteristics of Cd²⁺in three soils including raw soil, soil with organic matter removed and soil with calcium carbonate removed.Langmuir and Freundlich equations were used to describe the adsorption data,and to analyze the effects of organic matter and calcium carbonate on the absorption-desorption characteristics of Cd²⁺.The results showed that the absorption capacity of Cd²⁺in three soils increased with the increase of Cd²⁺concentration in the equilibrium solution.The adsorption rate of Cd²⁺increased firstly and then decreased with the increase of initial Cd²⁺concentration.The absorption capacity and adsorption rate of Cd²⁺followed the order: raw soil>soil with calcium carbonate removed>soil with organic matter removed.The adsorption data of the soils could be well described by Freundlich equation,but not the Langmuir equation in three soils.The desorption capacity and desorption rate of Cd²⁺increased with the increase of initial Cd²⁺content.The desorption capacity and desorption rate of Cd²⁺ followed the order: soil with organic matter removed>soil with calcium carbonate removed>raw soil.The desorption capacity was positively related to the adsorption capacity (P<0.01).When the adsorption capacity was constant,the desorption capacity of Cd²⁺followed the order: soil with organic matter removed>soil with calcium carbonate removed>raw soil.It can be concluded that the effect of organic matter on the absorption-desorption characteristics of Cd²⁺is greater than calcium carbonate in the typical acidic yellow loam soil in Guizhou.

Key words: Guizhou yellow loam soil, Cd²⁺, Organic matter, Calcium carbonate, Absorption;Desorption

中图分类号:

S155.2⁺⁴

陈芬, 余高, 张红丽, 侯建伟. 贵州典型黄壤土中有机质和碳酸钙对Cd²⁺吸附解吸特征的影响[J]. 河南农业科学, 2021, 50(5): 57-63.

CHEN Fen, YU Gao, ZHANG Hongli, HOU Jianwei. Effect of Organic Matter and Calcium Carbonate on Absorption-Desorption Characteristics of Cd²⁺ in Guizhou Yellow Loam Soil[J]. Journal of Henan Agricultural Sciences, 2021, 50(5): 57-63.

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贵州典型黄壤土中有机质和碳酸钙对Cd²⁺吸附解吸特征的影响

Effect of Organic Matter and Calcium Carbonate on Absorption-Desorption Characteristics of Cd²⁺ in Guizhou Yellow Loam Soil

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