河南农业科学 ›› 2020, Vol. 49 ›› Issue (2): 74-80.DOI: 10.15933/j.cnki.1004-3268.2020.02.010

• 农业资源与环境 • 上一篇    下一篇

1.5%苦参•蛇床素水剂在番茄和土壤中的最终残留及消解动态

陈妍   

  1. (商丘职业技术学院,河南 商丘 476000)
  • 收稿日期:2019-08-10 出版日期:2020-02-15 发布日期:2020-02-15
  • 作者简介:陈妍(1988-),女,河南商丘人,讲师,硕士,主要从事植物保护教学与科研。E-mail:cheny0604@163.com
  • 基金资助:
    河南省科技攻关项目(182102110371)

The Final Residues and Degradation Dynamics of 1.5% Matrine·Osthol AS in Tomato and Soil

CHEN Yan   

  1. (Shangqiu Vocational and Technical College,Shangqiu 476000,China)
  • Received:2019-08-10 Published:2020-02-15 Online:2020-02-15

摘要: 采用PSA固相萃取-高效液相色谱(HPLC)法,研究了露地和大棚条件下1.5%苦参•蛇床素水剂在番茄和土壤中的消解动态及最终残留,为番茄栽培中农药的安全使用提供参考。结果表明,2种栽培模式下苦参碱和蛇床子素的消解半衰期分别为5.18~6.70 d(番茄)、7.45~8.08 d(土壤)和1.70~1.99 d(番茄)、2.30~2.67 d(土壤)。距末次施药后1、3、7 d采样,苦参碱在番茄中的残留量为ND~0.427 4 mg/kg(露地)、0.010 2~0.522 8 mg/kg(大棚);蛇床子素在番茄中的残留量为ND~0.388 7 mg/kg(露地)、ND~0.395 2 mg/kg(大棚)。苦参碱和蛇床子素均属易降解农药,二者在大棚番茄和土壤中的消解半衰期均长于其在露地。在相同施药剂量、次数和采收间隔期下,除个别情况外,苦参碱和蛇床子素在大棚番茄和土壤中的最终残留量均高于其在露地的相应值。

关键词: 番茄, 苦参碱, 蛇床子素, 残留, 消解, 露地, 大棚

Abstract: The difference of degradation dynamics and final residues of 1.5%matrine·osthol AS in tomato and soil under open field and greenhouse conditions was studied,in order to provide theoretical references for pesticide usage in tomato and to improve safety procedure measures.The degradation dynamics and final residues were determined by HPLC with PSA solid phase extraction after 1.5%matrine·osthol AS was applied on tomato and soil in open field and greenhouse conditions. The results showed that,in two cultivation patterns the half-lives of degradation of matrine were 5.18—6.70 d in tomato and 7.45—8.08 d in soil,the half-lives of osthol were 1.70—1.99 d in tomato and 2.30—2.67 d in soil.The sampling time at 1,3,7 d after last pesticide application,the final residues of matrine in open field and greenhouse were ND—0.427 4 mg/kg and 0.010 2—0.522 8 mg/kg in tomato,and the final residues of osthol in open field and greenhouse were ND—0.388 7 mg/kg and ND—0.395 2 mg/kg in tomato,respectively.Matrine and osthol are easily degradable pesticides.The half-lives of degradation of matrine and osthol in greenhouse were longer than those in open field.With few exceptions,the final residues in tomato and soil in greenhouse were generally higher than in open field under the same application dosage,times and sampling interval.

Key words: Tomato, Matrine, Osthol, Residue, Dissipation, Open field, Greenhouse

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